xas-tools

**xas-tools** is a Python toolkit for X-ray absorption spectroscopy (XAS) simulation and analysis, providing tools for generating simulated XAS databases, analyzing XAS spectra, and interfacing with machine learning models for XAS predic…

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Overview

**xas-tools** is a Python toolkit for X-ray absorption spectroscopy (XAS) simulation and analysis, providing tools for generating simulated XAS databases, analyzing XAS spectra, and interfacing with machine learning models for XAS prediction from atomic structure.

Reference Papers

Reference papers are not yet linked for this code.

Full Documentation

Official Resources

  • Source Repository: https://github.com/atomisticnet/xas-tools
  • Documentation: Included in repository
  • License: Open source

Overview

xas-tools is a Python toolkit for X-ray absorption spectroscopy (XAS) simulation and analysis, providing tools for generating simulated XAS databases, analyzing XAS spectra, and interfacing with machine learning models for XAS prediction from atomic structure.

Scientific domain: X-ray absorption spectroscopy, ML-accelerated spectroscopy
Target user community: Researchers building and analyzing XAS databases, developing ML models for XAS prediction

Theoretical Methods

  • FEFF-based XAS simulation
  • Machine learning XAS prediction
  • XAS database construction
  • Spectral analysis and fitting
  • Atomistic structure-XAS mapping

Capabilities (CRITICAL)

  • XAS database generation
  • Simulated XAS spectra from structures
  • ML model training for XAS prediction
  • XAS spectral analysis
  • Structure-spectra mapping
  • High-throughput XAS computation
  • Support for multiple edges (K, L)

Sources: GitHub repository

Key Strengths

ML Integration:

  • Train ML models on XAS data
  • Predict XAS from structure
  • Accelerate XAS computation
  • Enable inverse design

Database Tools:

  • Build XAS databases
  • Manage spectral data
  • Standardize data formats
  • Enable data sharing

FEFF Integration:

  • Use FEFF for reference calculations
  • Automated FEFF workflow
  • Consistent calculation parameters

Inputs & Outputs

  • Input formats:

    • Atomic structures (ASE, POSCAR, CIF)
    • FEFF input files
    • ML training data
  • Output data types:

    • XAS spectra
    • ML model predictions
    • XAS databases
    • Spectral analysis results

Interfaces & Ecosystem

  • FEFF: XAS calculation backend
  • ASE: Structure handling
  • NumPy/Pandas: Data management
  • Scikit-learn/PyTorch: ML models

Performance Characteristics

  • Speed: Fast for ML prediction, moderate for FEFF
  • Accuracy: FEFF-level for simulation, ML-dependent for prediction
  • System size: Limited by FEFF for simulation
  • Memory: Low for ML, moderate for database

Computational Cost

  • ML prediction: Milliseconds per spectrum
  • FEFF simulation: Minutes per spectrum
  • Database construction: Hours to days
  • Typical: Very efficient with ML

Limitations & Known Constraints

  • FEFF-dependent: Requires FEFF for training data
  • ML accuracy: Depends on training data quality and coverage
  • Limited edges: Primarily K-edge focused
  • Documentation: Limited

Comparison with Other Codes

  • vs FEFF: xas-tools adds ML acceleration and database management
  • vs XANESNET: xas-tools is more general toolkit, XANESNET is specific DNN
  • vs Larch: xas-tools focuses on simulation, Larch on experimental data analysis
  • Unique strength: ML-accelerated XAS simulation and database tools, structure-spectra mapping

Application Areas

Battery Materials:

  • Lithium thiophosphate XAS
  • Transition metal redox tracking
  • Electrolyte characterization
  • Degradation monitoring

Catalysts:

  • Active site characterization
  • Oxidation state determination
  • Structure-spectra correlation
  • In situ/operando analysis

High-Throughput XAS:

  • Materials screening
  • XAS database construction
  • ML model training
  • Spectral libraries

Best Practices

ML Model Training:

  • Use diverse training data
  • Validate on held-out test set
  • Monitor prediction accuracy
  • Regularly update with new data

FEFF Calculations:

  • Use consistent parameters
  • Validate against experimental XAS
  • Include sufficient cluster size
  • Test convergence

Community and Support

  • Open source on GitHub
  • Developed at Brookhaven National Lab / AtomisticNet
  • Research code
  • Related publications available

Verification & Sources

Primary sources:

  1. GitHub repository: https://github.com/atomisticnet/xas-tools
  2. H. Guo et al., related publications from BNL

Confidence: VERIFIED

Verification status: ✅ VERIFIED

  • Source code: ACCESSIBLE (GitHub)
  • Documentation: Included in repository
  • Active development: Research code
  • Specialized strength: ML-accelerated XAS simulation, XAS database tools, structure-spectra mapping

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