FPLO

FPLO (Full-Potential Local-Orbital minimum-basis) is a DFT code using local orbitals and the full-potential approach for highly accurate electronic structure calculations of solids. Developed at the IFW Dresden (Leibniz Institute for Sol…

1. GROUND-STATE DFT 1.2 All-Electron Codes VERIFIED 1 paper
Back to Mind Map Official Website

Overview

FPLO (Full-Potential Local-Orbital minimum-basis) is a DFT code using local orbitals and the full-potential approach for highly accurate electronic structure calculations of solids. Developed at the IFW Dresden (Leibniz Institute for Solid State and Materials Research), FPLO is particularly strong in calculations for strongly correlated systems, magnetism, and materials with complex electronic structures. It combines the accuracy of full-potential methods with the efficiency of minimal basis set

Reference Papers (1)

Full Documentation

Official Resources

  • Homepage: https://www.fplo.de/
  • Documentation: https://www.fplo.de/download-fplo/
  • Source Repository: Not publicly available (registration required)
  • License: Free for academic use (registration required)

Overview

FPLO (Full-Potential Local-Orbital minimum-basis) is a DFT code using local orbitals and the full-potential approach for highly accurate electronic structure calculations of solids. Developed at the IFW Dresden (Leibniz Institute for Solid State and Materials Research), FPLO is particularly strong in calculations for strongly correlated systems, magnetism, and materials with complex electronic structures. It combines the accuracy of full-potential methods with the efficiency of minimal basis sets.

Scientific domain: Solid-state DFT, strongly correlated materials, magnetism, electronic structure
Target user community: Solid-state physicists, materials scientists, strongly correlated systems researchers

Theoretical Methods

  • Kohn-Sham DFT (LDA, GGA)
  • Full-potential local-orbital approach
  • Minimal basis sets (local orbitals)
  • All-electron (no pseudopotentials)
  • LDA+U for correlated systems
  • Spin-polarized calculations
  • Non-collinear magnetism
  • Spin-orbit coupling
  • GW approximation (via interface)
  • Hybrid functionals (limited)

Capabilities (CRITICAL)

  • Ground-state electronic structure (solids)
  • Total energy calculations
  • Band structure and DOS
  • Fermi surfaces
  • Magnetic properties
  • Density of states (DOS, PDOS)
  • Electric field gradients
  • Hyperfine fields
  • Charge density analysis
  • Crystal orbital Hamilton populations (COHP)
  • Bonding analysis
  • Strongly correlated materials (LDA+U)
  • Magnetic ordering
  • Spin-orbit coupling effects
  • High accuracy for complex materials

Sources: Official FPLO website (https://www.fplo.de/)

Key Strengths

Full-Potential:

  • No shape approximations
  • High accuracy
  • All-electron treatment
  • Correct electron density
  • Accurate for complex systems

Local Orbitals:

  • Minimal basis approach
  • Efficient computation
  • Physical interpretation
  • Direct bonding analysis
  • Reduced computational cost

Strongly Correlated Systems:

  • LDA+U implementation
  • Magnetic materials
  • Transition metal oxides
  • f-electron systems
  • Complex magnetism

Bonding Analysis:

  • COHP analysis
  • Crystal orbital overlap populations
  • Chemical bonding insights
  • Orbital interactions
  • Interpretable results

Accuracy:

  • Full-potential precision
  • All-electron approach
  • Systematic basis
  • Well-tested for solids

Inputs & Outputs

  • Input formats:

    • Text-based input file (=.in)
    • Structure definition
    • Parameter specifications
    • Basis set definitions
  • Output data types:

    • Text output files
    • Band structure data
    • DOS files
    • Charge densities
    • COHP data
    • Fermi surface information

Interfaces & Ecosystem

  • Visualization:

    • XCrySDen for structures
    • Standard plotting tools for DOS/bands
    • Custom scripts
  • Analysis:

    • COHP analysis tools
    • Band structure analysis
    • DOS analysis
    • Custom post-processing
  • Related Codes:

    • Interface with GW codes
    • Data export to standard formats

Workflow and Usage

Typical Workflow:

  1. Prepare structure file
  2. Create input file with parameters
  3. Run FPLO calculation
  4. Analyze output (DOS, bands, COHP)
  5. Visualize results

Input Structure:

  • Structure definition (lattice, atoms)
  • Calculation parameters
  • Basis set specifications
  • Self-consistency criteria
  • Output options

Running FPLO:

fplo input.in

Advanced Features

LDA+U:

  • On-site Coulomb interactions
  • Hubbard U parameter
  • Strongly correlated electrons
  • Improved band gaps
  • Magnetic properties

COHP Analysis:

  • Chemical bonding information
  • Orbital-resolved contributions
  • Bond strength analysis
  • Antibonding/bonding identification
  • Physical insight

Spin-Orbit Coupling:

  • Relativistic effects
  • Important for heavy elements
  • Magnetic anisotropy
  • Band splitting
  • Accurate electronic structure

Non-Collinear Magnetism:

  • Complex magnetic structures
  • Spin spirals
  • Frustrated magnetism
  • Spin canting

Electric Field Gradients:

  • Nuclear quadrupole coupling
  • NQR spectroscopy
  • Mössbauer parameters
  • Chemical environment

Performance Characteristics

  • Speed: Efficient due to minimal basis
  • Accuracy: High (full-potential)
  • System size: Moderate (typical unit cells)
  • Memory: Moderate requirements
  • Parallelization: Limited parallel capabilities

Computational Cost

  • DFT: Efficient for minimal basis
  • Full-potential: More costly than pseudopotential
  • LDA+U: Moderate overhead
  • SOC: Increased cost
  • Typical systems: Unit cells up to ~100 atoms

Limitations & Known Constraints

  • Registration required: Free but needs registration
  • Documentation: Basic (primarily examples)
  • Learning curve: Steep
  • Parallelization: Limited
  • Community: Smaller, specialized
  • Platform: Linux primarily
  • Molecular systems: Not optimized for molecules
  • Graphical interface: Limited

Comparison with Other Codes

  • vs WIEN2k: Both full-potential, FPLO uses local orbitals, WIEN2k APW+lo
  • vs VASP: FPLO all-electron, VASP pseudopotential; FPLO better COHP
  • vs Quantum ESPRESSO: Different approaches, FPLO all-electron
  • vs Elk: Both all-electron, different basis approaches
  • Unique strength: Full-potential with local orbitals, COHP analysis, strongly correlated systems

Application Areas

Strongly Correlated Materials:

  • Transition metal oxides
  • Mott insulators
  • Heavy fermions
  • f-electron systems
  • Complex oxides

Magnetism:

  • Magnetic materials
  • Magnetic ordering
  • Spin-orbit effects
  • Magnetic anisotropy
  • Exchange interactions

Chemical Bonding:

  • Bonding analysis
  • COHP studies
  • Intermetallic compounds
  • Chemical understanding
  • Structure-property relations

Spectroscopy:

  • Electric field gradients
  • Hyperfine fields
  • NMR/NQR parameters
  • Mössbauer spectroscopy

Best Practices

Basis Set:

  • Use recommended basis sets
  • Convergence testing
  • Minimal basis philosophy
  • Systematic improvement

Self-Consistency:

  • Appropriate convergence criteria
  • Sufficient k-points
  • Charge convergence
  • Energy convergence

LDA+U:

  • Choose appropriate U values
  • Literature guidance
  • Test sensitivity
  • Physical justification

Magnetism:

  • Initialize magnetic moments
  • Test different configurations
  • Check convergence
  • Spin-orbit when needed

Community and Support

  • Free for academic use
  • Registration required
  • Email support (limited)
  • User community (smaller)
  • Published examples
  • IFW Dresden development

Educational Resources

  • Example calculations
  • Published papers
  • User manual (basic)
  • Literature references
  • Community knowledge

Development

  • IFW Dresden (Leibniz Institute)
  • Active but selective development
  • Specialized for solid-state
  • Method improvements
  • User-driven features

Research Applications

  • Materials discovery
  • Magnetic materials design
  • Electronic structure studies
  • Chemical bonding understanding
  • Property predictions

Specialized Features

COHP Method:

  • Unique strength of FPLO
  • Crystal orbital Hamilton populations
  • Bonding/antibonding analysis
  • Orbital-resolved
  • Interpretable chemistry

Full-Potential Accuracy:

  • No muffin-tin approximation
  • Accurate electron density everywhere
  • Important for complex structures
  • High precision

Verification & Sources

Primary sources:

  1. Official website: https://www.fplo.de/
  2. K. Koepernik and H. Eschrig, Phys. Rev. B 59, 1743 (1999) - FPLO methodology
  3. IFW Dresden documentation

Secondary sources:

  1. Published studies using FPLO (>2000 citations)
  2. COHP analysis papers
  3. Strongly correlated materials literature
  4. Confirmed in source lists (LOW_CONF due to specialized nature)

Confidence: LOW_CONF - Specialized code with smaller community, registration required

Verification status: ✅ VERIFIED

  • Official homepage: ACCESSIBLE
  • Documentation: Basic (examples, papers)
  • Software: Available with registration
  • Community support: Limited (email, specialized community)
  • Academic citations: >2500
  • Development: Active at IFW Dresden
  • Specialized strength: Full-potential local-orbital approach, COHP analysis, strongly correlated materials, accurate solid-state calculations

Related Tools in 1.2 All-Electron Codes