TOMBO

TOMBO (TOhoku Mixed-Basis Orbitals) is an all-electron ab initio simulation code. It utilizes a unique mixed-basis set approach, combining plane waves with atomic orbitals. This allows it to accurately describe both the localized core el…

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Overview

TOMBO (TOhoku Mixed-Basis Orbitals) is an all-electron ab initio simulation code. It utilizes a unique mixed-basis set approach, combining plane waves with atomic orbitals. This allows it to accurately describe both the localized core electron states and the extended valence/conduction states, making it applicable to a wide variety of systems from clusters to periodic crystals.

Reference Papers (1)

Full Documentation

Official Resources

  • Homepage: https://www.tombo.page/
  • Documentation: https://www.tombo.page/doc
  • Source Repository: Distributed via website request or internal
  • License: Contact developers

Overview

TOMBO (TOhoku Mixed-Basis Orbitals) is an all-electron ab initio simulation code. It utilizes a unique mixed-basis set approach, combining plane waves with atomic orbitals. This allows it to accurately describe both the localized core electron states and the extended valence/conduction states, making it applicable to a wide variety of systems from clusters to periodic crystals.

Scientific domain: Clusters, crystals, surfaces, excited states Target user community: Researchers needing high-accuracy all-electron results and excited state properties (GW/BSE)

Theoretical Methods

  • Density Functional Theory (DFT)
  • Mixed Basis approach (Plane Waves + Atomic Orbitals)
  • All-Electron formulation
  • GW Approximation (GWA)
  • Bethe-Salpeter Equation (BSE)
  • Time-Dependent DFT (TDDFT)
  • Geometric Optimization

Capabilities

  • Electronic structure of isolated and periodic systems
  • Optical properties via GW-BSE
  • Molecular dynamics (MD)
  • Thermodynamic properties
  • Accurate treatment of core states

Key Strengths

Mixed Basis Set

  • Efficiently handles both core (localized) and valence (delocalized) electrons
  • Bridge between plane-wave codes and LCAO codes
  • Reduced computational cost compared to pure plane-wave all-electron methods for some systems

Excited States

  • Robust implementation of GW approximation and Bethe-Salpeter equation
  • Accurate prediction of optical absorption spectra

Inputs & Outputs

  • Input: Control files specifying basis limits, structure, and calculation type
  • Output: Energy eigenvalues, wavefunctions, optical spectra, forces

Computational Cost

  • Scaling: Standard cubic scaling for DFT, higher for GW/BSE.
  • Efficiency: Mixed basis reduces the cutoff energy required compared to pure PW codes.

Interfaces & Ecosystem

  • Availability:
    • Windows and Mac executables available for free download.
    • Source code available upon request to developers.
  • Input:
    • Detailed control files for basis and structure definition.

Advanced Features

  • Time-Dependent GW (TDGW):
    • Cutting-edge method for excited state dynamics.
  • LCAO + Plane Wave:
    • Unique hybrid basis set bridging gap between efficiency and accuracy.

Community and Support

  • Citation: Requires citation of Ono et al., Comp. Phys. Comm. 189, 20 (2015).
  • Documentation: Tutorial textbook and manual available on website.

Verification & Sources

Primary sources:

  1. Official Website: https://www.tombo.page/
  2. "TOMBO: All-electron mixed-basis ab initio simulation code"

Confidence: VERIFIED Status: Active Research Code

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